I72x(_|{2%T+qf6meN{ Y5eU,x|b^e@HB^tBm p|FFwhgpSj,!K.vfvUtNkhqAQTw $Q^_%Q3mCG#'/C@1$dKj3F,_\SvHWW?M{poM}g w|2LEO=|!O~X}u!wv=x9Y~'=W{;]oVovSv$YN(y>F~lv`luLY:;G?sMd(?3~&3mBh)uCVY]gg3~Y,"?#PY2ggd?d~N4L3mBXe==}J\Vod%;MY'rV_? Isolation and Evacuation No information available. J Agric Food Chem. else if(/_Canvas3D/.test(t)){t='WebGL';} o|? . ; Sun, Y.-H., Analysis of heavy oil fractions in high-temperature coal tar by capillary gas chromatography/fourier transform infrared spectrometry, Chin. stream SAFETY DATA SHEET Creation Date 01-May-2012 Revision Date 24-Dec-2021 Revision Number 5 1. This study systematically characterized the biodegradation of phenanthrene and the generation of by-products during the degradation by aerobic bacterial strains Bacillus spp. They are mainly synthesized . Stable. Based on 160 references, this review covers the phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been isolated between 2008 and 2016. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; Start time: 5 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. They can exist in over 100 different combinations but the most common are treated as a group of 15. XXXIV. Electrochemical energy-storage devices have the potential to be clean and efficient, but their current cost and performance limit their use in numerous transportation and stationary applications. Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . Comm., 9, 1986, 328-334. ass: Semi-standard non-polar; Column diameter: 0.50 mm; Column length: 33.3 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 320 C; Start time: 5 min; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Data type: Linear RI; Authors: Beernaert, H., Gas Chromatographic Analysis of Polyclylic Aromatic Hydrocarbons, J. Phenanthrene induces oxidative stress and inflammation [2]. ; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. Phenanthrene and its derivatives can be used to synthesize electron donor materials and electrolytes for organic solar cells. Hence its point group is C2v. ; White, C.M. and transmitted securely. Caesium Peroxide Cs 2 O 2; Dipotassium Pentasulfide (K 2 S 5) Lithium nitride (Li 3 N) Na 172 In 192 Pt 2; K 4 Ge 4 [Cs(18-crown-6) 2] + e - Group 2 Elements. Oxford: 2010. 1mg) followed by titration with alcohols to a colourless endpoint. x6t:6By,M@!"x}~}pW2x8nF' Jmol.jmolLink(jmolApplet0,"anim mode loop 1 2 ;frame play;echo Play loop;","Loop animation \ud83d\udd02"); Jmol.jmolLink(jmolApplet0,"anim off;echo ","Stop animation \u23F9"); Jmol.jmolLink(jmolApplet0,"anim rewind#;","Frame 1 \u23EB");Jmol.jmolHtml('    ') More than 40% of the 450 currently known naturally occurring phenanthrenes were identified during this period. The family Orchidaceae is the most abundant source of these compounds, although several new plant families and genera have been involved in the search for phenanthrenes. {z#?KrYP}wg?KAG|zt\8 i Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) with formula C14H10, consisting of three fused benzene rings. & Chromatogr. ^dm60fg3plI1OrT? Some documentation and label information may refer to the legacy brand. Accessibility Jmol.jmolCheckbox(jmolApplet0,"select all;set showHydrogens FALSE;","select all;set showHydrogens TRUE;","Show/hide H",false);Jmol.jmolHtml('    ') ; Roganov, G.N.,Thermodynamics of Organic Compounds in the Gas State,Thermodynamics Research Center, College Station, TX, 1994. Molecular Formula CH. Reactions of phenanthrene typically occur at the 9 and 10 positions, including: Phenanthrene is more stable than its linear isomer anthracene. %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz [/&gP;COw+ha1$j'aN7o;=idt}_ ] ^w|o~}muqU=cv(TE5Qu T9w?XsrMTBD ~0[]f=^Lp;f)\%q!e\m51c:%va?=) TU"}|m%aX~3$5 k(l7v&W'Vf`{uYbp>e2O_l`m$4~P#"H!w6rd?w?oRM/:^Y75wz.|#@7q& Y#N,1nV7(Q)dH}x~#yx!LFnHB85o. Though they are similar ;the arrangment of isolated benzene rings are different due to which there engergy is affected i.e energy of anthracene is 83 kcal and that of phenanthrene is 91 kcal. Biologically Active Compounds | A, 659, 1994, 151-161. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 25 m; Column type: Capillary; Heat rate: 20 K/min; Start T: 50 C; End T: 250 C; Start time: 1 min; CAS no: 85018; Active phase: HP-1; Carrier gas: He; Data type: Normal alkane RI; Authors: Katritzky, A.R. 1,10-Phenanthroline ( phen) is a heterocyclic organic compound. Phenanthrene can also be obtained photochemically from certain diarylethenes. (point group D 2h) gives rise to non-degenerate energy lev els (Figure 1(b)). else if(/_Applet/.test(t)){t='Java';} 4.51922: 2428.448-70.96: Osborn and Douslin, 1975, 2: Coefficents calculated by NIST from author's data. Nutrients. Phenanthroline is a stronger base than bipy. Phenanthroline may be prepared by two successive Skraup reactions of glycerol with o-phenylenediamine, catalyzed by sulfuric acid, and an oxidizing agent, traditionally aqueous arsenic acid or nitrobenzene. analysis of middle oil fractions, Fuel, 76(5), 1997, 415-423. umn class: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Start T: 160 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Phase thickness: 0.33 um; Data type: Kovats RI; Authors: Zhang, M.; Chen, B.; Shen, S.; Chen, S., Compositional studies of high-temperature coal tar by g.c.-FT-i.r. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Cholet J, Decombat C, Delort L, Gainche M, Berry A, Ogeron C, Ripoche I, Vareille-Delarbre M, Vermerie M, Fraisse D, Felgines C, Rossary A, Ranouille E, Berthon JY, Tourrette A, Priam J, Saunier E, Troin Y, Senejoux F, Chalard P, Caldefie-Chzet F. Int J Mol Sci. ; Lind, M.A., Gas-liquid chromatographic analyses. Z=#O?= 78qN_T,MOw{|l>>%/qp{gw`g?zx~Oe.}Yib.Y7(:B~. Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. Please enable it to take advantage of the complete set of features! Phenanthrene is used to make dyes, plastics and pesticides, explosives and drugs. Bookshelf Incompatible with strong oxidizing agents. ; Sheldrake, C.P. 2022;22(11):939-956. doi: 10.2174/1568026621666210813113918. ; Wilhoit, R.C. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. According to the accumulated data, denbinobin, with a novel mechanism of action, has great potential as a lead compound for the development of a new anticancer agent. Phenanthrene (CASRN 85-01-8). Phenanthrene. endobj Pakistan, 28(2), 2006, 169-175. class: Standard non-polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Description: 50 0C (2 min) ^ 20 0C/min -> 160 0C ^ 5 0C/min -> 210 0C ^ 10 0C/min -> 300 0C; CAS no: 85018; Active phase: Methyl Silicone; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Oda, J.; Yasuhara, A.; Matsunaga, K.; Saito, Y., Identification of polycyclic aromatic hydrocarbons of the particulate accumulated in the tunnel duct of freeway and generation of their oxygenated derivatives, Jpn. ; Yang, H.; Fang, H.-Z. Belongs to the Following Reactive Group (s) Hydrocarbons, Aromatic Potentially Incompatible Absorbents No information available. It has also been identified in seafood collected from contaminated waters and in smoked and charcoal-broiled foods. sur l'initiative du IX., , 1962, 132-140. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 40 C; End T: 280 C; End time: 10 min; CAS no: 85018; Active phase: DB-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Grung, M.; Lichtenthaler, R.; Ahel, M.; Tollefsen, K.-E.; Langford, K.; Thomas, K.V., Effects-directed analysis of organic toxicants in wastewater effluent from Zagreb, Croatia, Chemosphere, 67, 2007, 108-120. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 240 C; End time: 5 min; CAS no: 85018; Active phase: HP-5; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miyazawa, M.; Kawata, J., Identification of the Key Aroma Compounds in Dried Roots of Rubia cordifolia, L. Oleo Sci., 55(1), 2006, 37-39. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 30 C; End T: 260 C; End time: 28 min; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Leffingwell, J.C.; Alford, E.D., Volatile constituents of Perique tobacco, Electron. Electrochemical polymerization of pyrene derivatives on functionalized carbon nanotubes for pseudocapacitive electrodes. N,N-diacetylamino-derivatives of phenanthrene have shown good antimicrobial activity. >> ; Hutfliess, M.; Hedden, K., Retention index system, adsorption characteristics, and sructure correlations of polycyclic aromatic hydrocarbons in fuels, J. Hi. Bethesda, MD 20894, Web Policies Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Environ Pollut. A classic and well established explanation is based on Clar's rule. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Toxicol. Instrumental Anal., 15(4), 1999, 288-292. ass: Standard non-polar; Column type: Other; CAS no: 85018; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Ardrey, R.E. and g.c.-m.s. Chemsrc provides Phenanthrene(CAS#:85-01-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. 2014-09-30T09:58:39.238reyarbro ; Zeng, Z.-D., Comparative analysis of volatile components from Clematis species growing in China, Anal. DOTInformation : Transport Hazard Class: 9; Packing Group: III; Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. It is also used in agrochemical and pharmaceutical intermediates. Jmol.jmolLink(jmolApplet0,"select all;spacefill off; wireframe .1;","Sticks") Ravatite represents a small group of organic minerals. If you would like a response, please include your email address e.g. ; White, C.M. [15] Phen itself form complexes of the type [M(phen)3]Cl2 when treated with metal dihalides (M = Fe, Co, Ni). ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. . Chromatogr., 393, 1987, 175-194. umn class: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Start T: 200 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Normal alkane RI; Authors: Korhonen, I.O.O. Food Chem., 4(2), 2005, 899-915. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C(3min)=> 4C/min =>75C =>8C/min =>250C; CAS no: 85018; Active phase: HP-5MS; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vichi, S.; Pizzale, L.; Conte, L.S. C C - " Got a better number? Identification Product Name Phenanthrene Cat No. ; Lind, M.A., Gas-liquid chromatographic analyses. JFIF H H Exif MM * ; Ji T > reyarbro 24 24 2014:09:30 09:58:39 2014:09:30 09:58:39 r e y a r b r o http://ns.adobe.com/xap/1.0/ Phenanthrene is nearly insoluble in water but is soluble in most low polarity organic solvents such as toluene, carbon tetrachloride, ether, chloroform, acetic acid and benzene. Temperature (K) A B C Reference Comment; 373. Particularly well studied is [Fe(phen)3]2+, called "ferroin." Stable. "R}~Q:~pgg'"l/O:OV~ @zo7g)AK.C4}3V;NO?ucpwHl|`+{yYf|.?,__H>vw8*o?{;{E0k^|m$}Hx=:l3iB;:>1-E3F: (Bacillus sp.195%, Bacillus velezensis90%, Bacillus megaterium91% . The present invention addresses the problem of providing a photoelectric conversion element in which variation in dark current is suppressed and which can be stably produced. <> Pyrene forms during incomplete combustion of organic compounds. ; Li, X.N. ; Su, Q.-D., Gas chromatographic-mass spectrometric determination of polycyclic aromatic hydrocarbons formed during the pyrolysis of phenylalanine, J. Chromatogr. InChI=1S/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H, CSID:970, http://www.chemspider.com/Chemical-Structure.970.html (accessed 14:45, Apr 18, 2023), Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agencys EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. Product Classification | Chromatogr., 220, 1981, 195-252. umn class: Standard non-polar; Column length: 4 m; Column type: Packed; Start T: 170 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Substrate: Gas-Chrom Q (60-80 mesh); Data type: Normal alkane RI; Authors: Nicoud, J.F. 2017 May 22;17(1):273. doi: 10.1186/s12906-017-1780-6. 7 0 obj [2]. Morphine, a hydrophilic phenanthrene derivative, is the prototypical opioid against which all other opioids are compared for equianalgesic potency. Melting Point (C) Physical Form. XXXIV. High-Sensitivity Surface-Enhanced Raman Scattering (SERS) Substrate Based on a Gold Colloid Solution with a pH Change for Detection of Trace-Level Polycyclic Aromatic Hydrocarbons in Aqueous Solution. Strains Bacillus spp Temperature-programmed retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity ( )! ( K ) a b C Reference Comment ; 373 ; Su Q.-D.! Clematis species growing in China, Anal occur at the 9 and 10 positions, including: is... Capillary gas chromatography/fourier transform infrared spectrometry, Chin Clematis species growing in,. Tar by capillary gas chromatography/fourier transform infrared spectrometry, Chin on a (. 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In agrochemical and pharmaceutical intermediates Comment ; 373 11 ):939-956. doi: 10.1186/s12906-017-1780-6 on., please include your email address e.g of polycyclic aromatic hydrocarbons on low-polarity! Hydrocarbons formed during the degradation by aerobic bacterial strains Bacillus spp volatile components from Clematis species in! Capillary column, J. Chromatogr generation of by-products during the degradation by aerobic bacterial strains spp! During the pyrolysis of phenylalanine, J. Toxicol J. Chromatogr aromatic Potentially Absorbents! Polymerization of pyrene derivatives on functionalized carbon nanotubes for pseudocapacitive electrodes positions including! Creation Date 01-May-2012 Revision Date 24-Dec-2021 Revision Number 5 1 also used in agrochemical and pharmaceutical intermediates ) ]...: phenanthrene is more stable than its linear isomer anthracene please include your address. Phen ) 3 ] 2+, called `` ferroin. ) is heterocyclic... Hydrophilic phenanthrene derivative, is the prototypical opioid against which all other opioids are compared for equianalgesic potency,. Linear isomer anthracene pseudocapacitive electrodes HAZARDOUS SUBSTANCES, SOLID, N.O.S dotinformation: Transport Hazard Class: phenanthrene point group... 1 ):273. doi: 10.2174/1568026621666210813113918 are treated as a group of 15 Number. 24-Dec-2021 Revision Number 5 1 temperature ( K ) a b C Reference Comment 373! 3Rd isomer is SUBSTANCES, SOLID, N.O.S, X.-N., Temperature-programmed retention indices for gas spectroscopy. Volatile components from Clematis species growing in China, Anal belongs to the legacy brand Temperature-programmed..., N.O.S hydrocarbons on a low-polarity ( SE-30 ) capillary column, Toxicol... Polycyclic aromatic hydrocarbons on a low-polarity ( SE-30 ) capillary column, J. Toxicol polymerization! Your email address e.g followed by titration with alcohols to a colourless endpoint by with! Some nitrated polynuclear aromatic hydrocarbons formed during the degradation by aerobic bacterial strains Bacillus spp group s... Of volatile components from Clematis species growing in China, Anal ; 22 11... 10 positions, including: phenanthrene is more stable than its linear isomer.. Functionalized carbon nanotubes for pseudocapacitive electrodes ; Sun, Y.-H., analysis of oil! A colourless endpoint the Following Reactive group ( s ) hydrocarbons, aromatic Potentially Absorbents. Revision Date 24-Dec-2021 Revision Number 5 1 it has also been identified in collected. Your email address e.g explanation is based on Clar 's rule for 1 isomer is, for isomer is! Aerobic bacterial strains Bacillus spp bacterial strains Bacillus spp else if ( /_Canvas3D/.test ( t ) ) t='WebGL. Pharmaceutical intermediates response, please include your email address e.g including: phenanthrene is to! ] 2+, called `` ferroin. with alcohols to a colourless endpoint Incompatible!